Reologie - Fluide Tixotrope

Definition

Thixotropy is the property of some non-newtonian pseudoplastic fluids to show a time-dependent change in viscosity; the longer the fluid undergoes shear stress, the lower its viscosity. A thixotropic fluid is a fluid which takes a finite amount of time to attain equilibrium viscosity when introduced to a step change in shear rate. However, this is not a universal definition; the term is sometimes applied to pseudoplastic fluids without a viscosity/time component. Many gels and colloids are thixotropic materials, exhibiting a stable form at rest but becoming fluid when agitated.

It is important to note the distinction between a thixotropic fluid and a shear thinning fluid. The former displays a decrease in viscosity over time at a constant shear rate, while the latter displays decreasing viscosity with increasing shear rate. Fluids which exhibit the opposite property, in which shaking for a time causes solidification, are called rheopectic, sometimes called anti-thixotropic, and are much less common.

Natural examples

Some clays are thixotropic, with their behavior of great importance in structural and geotechnical engineering. In earthquake zones, clay-like ground can exhibit characteristics of liquefaction under the shaking of a tremor, greatly affecting earth structures and buildings. Similarly, a lahar is a mass of earth liquefied by a volcanic event, which rapidly solidifies once coming to a rest. Drilling muds used in geotechnical applications can be thixotropic. Landslides, such as those common in the cliffs around Lyme Regis, Dorset and in the Aberfan slag heap disaster in Wales are evidence of this phenomenon. Also honey from honey bees may exhibit this property under certain conditions.

Another example of a thixotropic fluid is the synovial fluid found in joints between some bones. The ground substance in the human body is thixotropic.

Etymology

The word comes from Greek thixis, touch (from thinganein, to touch) + -tropy, -tropous, from Greek -tropos, of turning, from tropos, changeable, from trepein, to turn.

Applications

Ketchup displays thixotropic properties.

Examples of applications for thixotropic fluids are the thickening of food stuffs and medical products. Toothpaste is thixotropic, which allows it to be squeezed out of the tube, yet retain a solid shape on the brush. Ketchup is frequently thixotropic.

Modern alkyd and latex paint varieties are often thixotropic and will not run off the painter's brush, but will still spread easily and evenly, since the gel-like paint "liquefies" when brushed out. Many clutch-type automatic transmissions use fluids with thixotropic properties, to engage the different clutch plates inside the transmission housing at specific pressures, which then changes the gearset.

Laponite, a mixture of water and synthetic clay, is used in the lubrication of robotic snails/slugs (gastropods), which rely on Laponite's thixotropic property for locomotion.

About thixotropy

- A physical property usually associated with certain gels whose molecular bonds are disrupted by movement.

- May help explain skeletal muscle’s viscous behaviour

- Attributed to formation of "weak" actin-myoisin cross-bridges in resting muscle

PROPERTIES ASSOCIATED WITH THIXOTROPIC MATERIALS:

- Stiffness depends on recent history of movement.

- Stiffness increases with

Prior immobility / stillness

- Stiffness decreases with

Prior movement

Tetanic isometric stimulation

Determining And Measuring Thixotropy and Rheology For Coatings Applications